The date on the eticket does not matter. A date has to be entered but it is not necessarily the date of travel. What matters is that you list her for the correct flight on the BA staff travel website. If she does not get on, just make sure that she asks the agent to "roll her over" to the following day's flight. You should not have to relist again. She can check in at a kiosk at LHR using the PNR number. There is a separate staff travel desk at T5 if she is checking a bag.
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